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Sulfuric acid h2so4

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Sulfuric acid (H2SO4) is a colorless, dense, and highly corrosive liquid chemical compound. It is a strong mineral acid that is commonly used in various industrial and laboratory applications.

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29 protocols using sulfuric acid h2so4

1

Fabrication of Gold Nanoparticle-Functionalized Slides

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All the chemicals used in this article were of analytical grade. Gold(iii) chloride trihydrate (HAuCl4·3H2O, 99.9%), sodium citrate tribasic dihydrate (HOC(COONa)(CH2COONa)2·2H2O, 99.0%), and (3-aminopropyl)trimethoxysilane (H2N(CH2)3Si(OCH3)3, APTMS, 97%) were provided by Sigma-Aldrich Co., Ltd (USA). Sodium hydroxide (NaOH, 96%) was provided by Guangdong Guanghua Sci-Tech Co., Ltd (China). Deionized water (DI, resistivity: 18 MΩ cm, Thermo Scientific Easypure II, Göteborg, Sweden) was synthesized in the Center for Innovative Materials and Architectures (INOMAR), Vietnam National University, Ho Chi Minh City (VNUHCM). Hydrogen peroxide (H2O2, 30%) was obtained from Merck KGaA (Germany). Sulfuric acid (H2SO4, 96%) was acquired from Acros Organics (USA). Ethanol (C2H5OH, EtOH, 99.8%) and methanol (CH3OH, 99.8%) were procured from Fisher Ltd (UK). Microscope glass slides (soda-lime glass, chemical composition: SiO2 = 75 ± 5 wt%; Na2O = 15 ± 2 wt%; CaO + MgO = 10 ± 2 wt%) were purchased from ISOLAB Laborgeräte GmbH, Eschau, Germany.
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2

Quantification of Organic Pollutants in Water

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Metaldehyde (99+% purity) was obtained from Acros. Carbetamide and mecoprop (99+% purity) were obtained from Sigma Aldrich. Purelab Option-S7/15 system (Elga process water, Buckinghamshire, UK) supplied the ultra-pure water.
Sodium hypochlorite (NaClO) 13%, and methanol (HPLC grade) and ammonium formate (99+% purity) used for the mobile phases were provided by Fisher Scientific. Samples were quenched using sodium thiosulfate (Na2S2O3, 99% purity) also provided by Fisher Scientific. For THM determination, potassium dihydrogenphosphate (KH2PO4) and disodium hydrogenphosphate (Na2HPO4) were obtained from Acros. Sodium sulphite (Na2SO3, 99+% purity) and sodium sulphate (Na2SO4, 99+% purity) were provided by Fisher Scientific. 1,2,3 trichloropropane, 1,4 bromofluorobenzene, THM calibration mix (EPA 501/601 chloroform, bromodichloromethane chlorodibromomethane and bromoform, compound at 2.0 mg/mL in methanol), HAA calibration mix (EPA 552.2 monochloroacetic acid, dichloroacetic acid, trichloroacetic acid, chlorobromo acetic acid, dichlorobromo acetic acid, chlorodibromo acetic acid, monobromo acetic acid, dibromo acetic acid and tribromo acetic acid each compound at 2.0 mg/mL concentration in methyl tert-butyl ether) and methyl tert-butyl ether (HPLC grade) were obtained from Sigma Aldrich. Sulfuric acid (H2SO4) and sodium hydroxide (NaOH, laboratory grade) were obtained from Acros.
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3

Synthesis of Lead Halide Perovskite Nanocrystals

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Cesium carbonate (Cs2CO3), 1-octadecene (ODE, C18H36), oleylamine (OAm, C18H37N), hexadecyltrimethylammonium
bromide (CTAB, C19H42BrN), and sulfuric acid
(H2SO4) were obtained from Acros Organics. Lead(II)
bromide (PbBr2) was acquired from Fisher Scientific company.
Oleic acid (OA, C18H34O2) and hexane
(C6H14) were purchased from Sigma Aldrich. Quinine
anhydrous (C20H24N2O2)
was acquired from Fluka Analytical.
All chemicals were used
as received without further purification.
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4

Enoxacin Degradation via Electro-Fenton

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Enoxacin (1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro-1,8-naphthyridine-3carboxylic acid) was generously provided by the LNCM (Laboratoire National de Contrôle des Médicaments -Tunis, Tunisia) (structure displayed in Fig. 1). FeSO 4 •7H 2 O (purity 99%) and Na 2 SO 4 (purity 99%) were used as catalyst and a supporting electrolyte respectively and were purchased from Acros Organics (Thermo Fisher Scientific, Illkirch, France). Acetonitrile (purity 99.9%) (HPLC grade) was obtained from Sigma-Aldrich (Saint Quentin Fallavier, France). The initial pH of the solutions was adjusted to 3, the optimal pH value for the electro-Fenton process (Diagne et al., 2007) , by adding analytical grade sulfuric acid H 2 SO 4 purchased from Acros Organics. All solutions were prepared with ultrapure water and all the other chemicals used for analysis were supplied from Acros Organics and Sigma Aldrich.
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5

Extraction and Analysis of Ipomoea aquatica

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Methanol (MeOH) (HPLC grade), acetonitrile (ACN) (HPLC grade), glacial acetic acid (AA) (100 %), dimethyl sulfoxide (DMSO), and anisaldehyde were purchased from Merck (Darmstadt, Germany); trifluoroacetic acid (TFA) (≥98%), diethylamine (DEA) (≥99.5%) and methanol-d4 (99.8% D) from Sigma-Aldrich (St. Louis, MO, USA); MeOH AnalaR NORMAPUR ® (analytical reagent) from VWR (Fontenay-sous-Bois, France), n-hexane from SDFCL (Maharashtra, India), dichloromethane (DCM) (99.5%) from BDH (Leicestershire, UK), and ethyl acetate (EA) (99.9%) from ROMIL (Cambridge, UK); sulfuric acid (H2SO4) (96% solution in water) was obtained from Acros Organics (New Jersey, USA) and ultrapure water was produced by an Arium pro ultrapure water system (Sartorius, Gottingen, Germany). The fresh plants of Ipomoea aquatica (aerial parts) were collected in Darfur, West Sudan in March 2010. A voucher specimen was deposited in the Herbarium of the Botany Department, Faculty of Science, University of Khartoum, Sudan.
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6

Synthesis of Hybrid Electrochemical Catalysts

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All chemicals were used as received without further purification: potassium permanganate (KMnO4, QReC), ammonium sulfate ((NH4)2SO4, Sigma-Aldrich), urea (Ajax Finechem), choline chloride (Sigma-Aldrich), zinc chloride (ZnCl2, Ajax Finechem), zinc sulfate (ZnSO4, Ajax Finechem), carbon cloth (AvCarb 1071 HCB, AvCarb Material Solutions), deionized water, isopropyl alcohol (IPA, Ajax Finechem) and nickel foam (99.97%, 100 pores per inch (PPI) and 1 mm thick, Qijing Trading Co., Ltd.), sulfuric acid (H2SO4, Ajax Finechem).
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7

Electrochemical Synthesis of Zinc Compounds

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All chemicals were used as received without further purification: potassium permanganate (KMnO4), QRëC, Auckland, New Zealand; ammonium sulfate ((NH4)2SO4), Sigma-Aldrich, St. Louis, MO, USA; carbon cloth (AvCarb 1071 HCB), AvCarb Material Solutions, Lowell, MA, USA; deionized (DI) water; isopropyl alcohol (IPA), Ajax Finechem, Auckland, New Zealand; sulfuric acid (H2SO4), Ajax Finechem, Auckland, New Zealand; zinc trifluoromethanesulfonate (Zn(OTf)2), Sigma-Aldrich, St. Louis, MO, USA; and Dimethyl sulfoxide (DMSO), Sigma-Aldrich, St. Louis, MO, USA.
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8

Electrochemical Characterization of RTIL

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The RTIL 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C 2 mim][NTf 2 ]) was purchased from Merck (Kilsyth, Vic, Australia) at ultra-high purity electrochemical grade, and used as received. Poly(methyl methacrylate) (PMMA, average MW ca. 15 000, Sigma-Aldrich Pty Ltd, NSW, Australia), tetra-N-butylammonium perchlorate (TBAP, >99.0%, Sigma-Aldrich) and ferrocene (Fc, 98%, Sigma-Aldrich) were also used as received. Acetone (≥99.9%, Sigma-Aldrich), acetonitrile (MeCN, 99.8%, Sigma-Aldrich), ethanol (EtOH, Sigma-Aldrich, 99%), and ultrapure water (with a resistivity of 18.5 MΩ cm prepared by a Milli-Q laboratory water purification system (Millipore Pty Ltd, North Ryde, NSW, Australia) were used for rinsing the microdisk electrode after polishing. Highpurity oxygen gas (O 2 , >99.5%) and high-purity nitrogen gas (N 2 , 99.99%) were purchased from BOC gases (North Ryde, NSW, Australia). Aqueous solutions of 0.5 M sulfuric acid (H 2 SO 4 , 95-98 wt%, Ajax Finechem, WA, Australia) for activating electrodes were prepared in ultrapure water.
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9

Carbon Nanotube Electrochemical Characterization

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All solutions were prepared with distilled/deionized water (18 MΩ resistivity, Darmstadt, Germany). Carbon nanotubes were obtained from Material Science & Nanotechnology Laboratory (IVIC, Caracas, Venezuela). Nitric acid (HNO3, 69.2 wt.%) and hydrogen peroxide (H2O2, 30%V/V) were purchased from Sigma-Aldrich Sigma, (Darmstadt, Germany). Potassium phosphate monobasic (KH2PO4) and sodium hydroxide (NaOH, 99.9% p/p) were purchased from Fisher Scientific (Waltham, MA, USA). Phosphate-buffered saline (PBS, 20 mmol·L−1 KH2PO4 + 20 mmol·L−1 K2HPO4 + 0.1 mol·L−1 KCl, pH 6.8) was used as a supporting electrolyte. Potassium ferricyanide (K3[Fe(CN)6]), iron trichloride hexahydrated (FeCl3·6H2O), and potassium chloride (KCl) were from BDH Chemicals (Philadelphia, PA, USA), hydrochloric acid (HCl, 37%) was from Fisher Scientific (Waltham, MA, USA), glassy carbon (GC, diameter ( Φ=3 mm ), geometric area = 0.0706 cm2), silver/silver chloride reference electrode (Ag/AgCl), and graphite rod counter-electrode were from CH-Instruments (Austin, TX, USA), sulfuric acid (H2SO4, 98%) was from Fisher Scientific (Waltham, MA, USA), and 1 µm, 0.3 µm, and 0.05 µm alumina powder were from CH-Instruments (Austin, TX, USA), dimethylformamide (DMF) was from BDH Chemicals (Philadelphia, PA, USA), poly (diallyldimethylammonium chloride) (PDDA, 4% w/w in water) were from Sigma.
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10

Fluorescent Organometallic Synthesis

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Ethanol (CH3OH, 99.8%, Fisher Scientific), toluene (C6H5CH3, 99.9%, Fluka), fluoresceinamine (6-aminofluorescein, ≥90%, Aldrich), chloroplatinic acid hexahydrate (H2PtCl6·6H2O, ACS reagent, Sigma-Aldrich), formic acid (98%, Fluka), sulfuric acid (H2SO4, 98%, Fisher Scientific) were all used as received. Ferrocene (C10H10Fe, 98%, Aldrich) was resublimed at 90 °C prior to use. Argon (Ar, 99.99%), was obtained from BOC. Ultra-high purity water (Millipore MilliQ, 18 MΩ cm) was used for all aqueous solutions.
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