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3 protocols using molybdenum hexacarbonyl mo co 6

1

Synthesis of Graphite-based Catalysts

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Graphite powder (100 mesh, 99.9995%) was purchased from Alfa Aesar. Orthophosphoric acid (H3PO4, 85%) was purchased from Fisher Scientific. Sulfuric acid (H2SO4, 95–97%), potassium permanganate (KMnO4, 99%), molybdenum hexacarbonyl (Mo(CO)6, 98%), thiourea (SC(NH2)2, 99%) and cobalt nitrate hexahydrate (Co(NO3)2 6H2O, 98%) were purchased from Sigma-Aldrich. Pt@C (20 wt% on Vulcan) was acquired from Premetek. Absolute ethanol (CH3CH2OH, 99.96%) was purchased from VWR. All chemicals were used as received. Deionized water (Milli-Q, 18.25 MΩ) was obtained through an EMD Millipore water purification system.
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2

Synthesis of Transition Metal Complexes

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Molybdenum hexacarbonyl Mo(CO)6 (98.0%), tetraethylthiuram disulfide (≥97%), ammonium tetrathiotungstate (≥99.99%), sodium diethyldithiocarbamate trihydrate (≥98%), sulfur (≥99.98%), ammonium sulfide (20 wt% in water), tetraethylammonium bromide (≥99%), ammonium perrhenate (≥99.0%), bis(diethylthiocarbamoyl)disulfide (≥97%), manganese(II) acetate tetrahydrate (≥99%), chromium(III) chloride hexahydrate (≥96%), and silica gel (40–63 µm particle size) were purchased from Sigma–Aldrich and used without further purification. Acetone (≥99.0%) dichloromethane (≥99.0%), methanol (≥99.5%), diethyl ether (≥99.0%), acetonitrile (≥99.9%), hexane (≥97.0%), dry acetonitrile (≥99.80%), pentane (≥99.0%), isopropanol (≥99.5%), and hydrochloric acid (37%) were purchased from Sigma–Aldrich and used as received.
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3

Synthesis of Functional Nanomaterials

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All of the chemicals used in this work, including graphite powder, sodium nitrate (NaNO3), potassium permanganate (KMnO4), hydrogen peroxide (H2O2, 30%), l-ascorbic acid (L-AA, Sigma-Aldrich, Seoul, Korea), molybdenum hexacarbonyl (Mo(CO)6, Sigma-Aldrich), selenium (99.999%, Sigma-Aldrich), oleic acid (OA, 85%, Fluka, Mexico City, Mexico), oleylamine (OAm, 80–90%, Acros Organics, Geel, Belgium), and dodecanethiol were of analytical grade and used as received without further purification.
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