chemicals were of analytical
grade and used without further purification. Ammonium hydroxide [NH4OH] solution (25%, Sigma-Aldrich), calcium nitrate tetrahydrate
[Ca(NO3)2·4H2O] (98%, Sigma-Aldrich),
and di-ammonium hydrogen orthophosphate [(NH4)2HPO4] (98%, Sigma-Aldrich) were used to synthesize neat
HAP. Chitosan (85%, deacetylated medium molecular weight, Sigma-Aldrich),
carboxymethyl cellulose (low viscosity, Sigma-Aldrich), sodium alginate
(low viscosity, Sigma-Aldrich), and gelatin type B (medium bloom,
SRL) were used in the synthesis process of HAP-biopolymer nanocomposites.
Cadmium nitrate (Sigma-Aldrich), lead nitrate (Merck), sodium fluoride
(99.5%, Merck), and sodium arsenate (99%, Merck) were used to prepare
the pollutant stock solutions.