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4 protocols using c10h16n2o8

1

Synthesis of π-SnS Nanoparticles

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The analytical reagents employed in this study were tin (II) chloride (SnCl2·2H2O, Sigma-Aldrich), thioacetamide (C2H5NS, Sigma-Aldrich, St. Louis, MO, USA), ethylenediaminetetraacetic acid (EDTA, C10H16N2O8, Sigma-Aldrich, St. Louis, USA), and acetone (C3H6O, Sigma-Aldrich, St. Louis, USA), used as received without further purification and stored in a humidity-controlled desiccator cabinet. For the preparation of π-SnS nanoparticles, SnCl2·2H2O and C2H5NS were used as Sn and S sources, respectively, and C10H16N2O8 was used as a chelating agent.
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2

Titanium-based Photocatalyst Synthesis

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All chemicals were of analytical grade and used without further purification: titanium (IV) i-propoxide (TTIP, Merck, Kenilworth, NJ, USA, 98%), hydrochloric acid (HCl, Chemsolute, Th. Geyer, Berlin, Germany, 35–38%), cinnamic acid (C9H8O2, Reachim, Moscow, Russia, 99%), ibuprofen sodium salt (C13H17O2Na, Sigma-Aldrich, St. Louis, MA, USA, 98%), ethylenediaminetetraacetic acid (C10H16N2O8, Sigma-Aldrich, 99%), i-propanol (C3H8O, Sigma-Aldrich, >99%), tert-butanol (C4H10O, Sigma-Aldrich, 99%), benzoquinone (C6H4O2, Sigma-Aldrich, ≥98%), and titania P25 (TiO2, Evonik, Essen, Germany, 99.5%).
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Synthesis of Copper Nanoparticles

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Copper sulfate, CuSO4 (≥98%); sodium borohydride, NaBH4 (98%);
ethylenediaminetetraacetic acid, EDTA, C10H16N2O8 (≥98%); potassium hydroxide, KOH
(90%); sodium dodecyl sulfate, SDS (≥99%); and poly(vinylpyrrolidone),
PVP-300 K (99%) were purchased from Sigma-Aldrich Peru (Lima, Peru).
All chemicals were of analytical purity and used as received without
further purification. Milli-Q water (18 MΩ cm) was used in all
experimental syntheses. The purification system (Millipore, Darmstadt,
Germany) is located in our laboratory.
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4

Synthesis of Cerium-Neodymium Oxide Nanocomposites

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Ce1−xNdxO2−δ (x = 0, 0.05, 0.1 and 0.2) were synthesized by the combined EDTA–citrate complexing method.22 (link) Firstly, stoichiometric amounts of the corresponding metal nitrates (Ce(NO3)3·6H2O, 99.0% Sigma-Aldrich and Nd(NO3)3·6H2O, 99.9% Sigma-Aldrich) were dissolved in deionized water. The solution was heated to 70 °C and stirred during 1 h. Anhydrous citric acid (C6H8O7 99.98%, Sigma-Aldrich) and EDTA (C10H16N2O8 98.5%, Sigma-Aldrich) were separately dissolved in an ammonium hydroxide dissolution (NH4OH 28–30%, Sigma-Aldrich), controlling the pH value at around 7. Then, these two solutions were heated to 90 °C under stirring and subsequently dropped simultaneously to the aqueous metal nitrates-containing solution. The pH of the resultant solution was monitored and keep at around 7 by dropping an excess of aqueous ammonia solution. The molar ratio was 1 : 1 : 1 for metal cations : citric acid : EDTA. A transparent solution was obtained and subsequently heated to 90 °C, while it was stirred. After water evaporation, a viscous gel was obtained. Then the gel was combusted at about 300 °C to remove the organic matter. The resultant yellow powder was calcined at 500 °C for 8 h under air atmosphere.
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