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4 protocols using terephthalic acid

1

Synthesis of Chromium-Based MOF

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All reagents were commercially available and used as received without further purification. Analytical-grade Cr(NO3)3·9H2O (>99%), terephthalic acid (>99%) and N,N-dimethylformamide (DMF) (>98%) were purchased from J&K Scientific Ltd. Cr2O3 powder (>99%) was purchased from Thermo Fisher Scientific Ltd. Hydrofluoric acid (40%) and formaldehyde solution (38%) was obtained from Beijing Chemical Co., Ltd. (Beijing, China).
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2

Enzymatic Synthesis of Organic Compounds

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Terephthalic acid (99%), trimesic acid (99%), cystamine hydrochloride, and 2,3,4,5,6-pentafluorobenzyl bromide (99%) were purchased from J&K Scientific Ltd. (Beijing, China). Chromium nitrate, copper(II) acetate, and L-glutamic acid were bought from Sinopharm Chemical Reagent Co., Ltd. (Beijing, China). Carbonic anhydrase (CA, bovine red blood cell), formate dehydrogenase (FateDH, lyophilized), and glutamate dehydrogenase (GDH, bovine liver) were provided by Sigma-Aldrich (St. Louis, MO, USA). Nicotinamide adenine quinone dinucleotide (NADH, 98%) was obtained from Aladdin Biotechnology Co., Ltd. (Shanghai, China). CO2 (>99%) and 13CO2 (>99%) were purchased from Beijing Ruyuan Ruquan Technology Co., Ltd. (Beijing, China). All other chemicals were obtained from Beijing Chemical Factory (Beijing, China). Double-distilled water was used in all experiments.
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3

Synthesis of Nitro-Alcohols via Zr-Ru Catalysis

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Terephthalic acid and ZrCl4 were obtained from J&K Scientific. RuCl3·3H2O was supplied by Xi’an Catalyst Chemical Co., Ltd.
The nitro compounds and alcohols were obtained from Alfa Aesar China
(Tianjin) Co., Ltd. All reagents were of analytical grade and used
without further purification.
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4

Synthesis of Polyester Precursors

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N,N-dimethylformamide (DMF, 99.8%), Terephthalic acid (TPA, 99%), and Ferric nitrate nonahydrate (Fe(NO3)3·9H2O, 95%) were all purchased from J&K Scientific Ltd. (Beijing, China). ethanol (EtOH, 95%) was purchased from Beijing Tongguang Co., and 3-hydroxyphenyl-phosphinyl propanoic acid (CEPPA) was provided by Zhenbei Co., Ltd. (Hangzhou, China). Pure Terephthalic acid (PTA, industrial grade) and Ethylene glycol (EG, industrial grade) were supplied by the Sinopec Group (Tianjin, China). Triphenyl phosphite (TPI, analytical pure) and Diantimony trioxide (Sb2O3, analytical pure) were purchased from Macklin Biochemical Co., Ltd. (Shanghai, China). HyMax 1010 (1010, industrial grade) was provided by Langyi Functional Materials Co., Ltd. (Shanghai, China). All chemicals were used directly without further purification.
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