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5 protocols using polysulfone

1

Synthesis and Characterization of Ag/CQD Nanocomposite

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Eureka lemon, ethanol (C2H5OH, Sigma Aldrich, Darmstadt, Germany), and dichloromethane (CH2Cl2, Merck, Darmstadt, Germany) were used to synthesize CQD solution. Silver nitrate (AgNO3, Sigma Aldrich) and sodium borohydride (NaBH4, Sigma Aldrich) were utilized for the synthesis of pure Ag and Ag/CQD nanomaterial. Tartrazine (Dye content ≥ 85%, Sigma Aldrich) was used as the dye pollutant. Besides, sodium hypochlorite (NaOCl, Sigma Aldrich) was applied as membrane cleaning agent. Polysulfone (PSF, Solvay, GA, USA), polyvinylpyrrolidone (PVP, 160,000 g/mol, Sigma Aldrich) and N-methyl-2-pyrrolidone (NMP, Merck) were used for the fabrication of composite membrane.
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2

Polysulfone Ultrafiltration Membrane Fabrication

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Polysulfone (PSF) for making ultrafiltration membrane was supplied from Solvay. Bovine serum albumin (BSA) (69 kDa) and lysozyme (12 kDa) were obtained from HiMedia Laboratories Pvt Ltd., Mumbai, Maharashtra 400086, India, coliform agar and NMethyl-2-pyrrolidone (NMP) was obtained from Merck KGaA, Darmstadt, Germany. Silver (20, 40, and 90–210 nm) nanoparticles, as shown in Figure 1 [31 ,32 ,33 ], were obtained from Nanostructured & Amorphous Materials, Inc., Katy, TX 77494, USA. Pure water was used for the membrane’s fabrication and water flux test.
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3

Chloromethylated Polysulfone for Dye Removal

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Polysulfone (PSf, MW =
80 kDa) was supplied by Solvay Co. Ltd. (Shanghai). Chloromethylated
Polysulfone (CMPSf) with a degree of substitution (DS)26 (link) of 22% was prepared according to our previous
work.44 (link)meso-Tetraphenylsulfonato
porphyrin (TPPS) was purchased from J&K Scientific Ltd. Rhodamine
B (RhB), methylene blue (MB), and methyl orange (MO) were purchased
from Tianjin Guangfu Fine Chemical Research Institute. All other chemicals
were of analytical grade and used as received.
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4

Synthesis of Polysulfone Membranes

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Bisphenol A (BPA, 99%), dimethylamine (40%), polyethylene glycol (PEG, Mn~400 g/mol), potassium carbonate (K2CO3, ≥99%) were obtained from Aladdin. The 4,4-difluorodiphenylsulfone (DFDPS), 1,3-propane sultone, bovine serum albumin (BSA, ≥98%), deuterated dimethyl sulfoxide (DMSO-d6) and deuterated chloroform (CDCl3) were purchased from Sigma-Aldrich. N-Methyl-2-pyrrolidone (NMP), toluene, formaldehyde, Na2HPO4·12H2O, KH2PO4·2H2O were all purchased from Aladdin. Polysulfone (PSf, Mn~80,000 g/mol) was provide by Solvay, China.
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5

Polyamide Thin-Film Composite Membranes

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Aluminium nitrate and ammonium hydroxide solution (NH4OH) were purchased from Merck Chemicals Co., Darmstadt, Germany. Polysulfone was purchased from Solvay advanced polymers, USA. M-phenylenediamine (99.4%), n-hexane (high purity, 97%), Polysorbates-80 (polyoxyethylene sorbitan monooleate, Tween-80), Trimesoyl chloride (98.5%), Sodium laurylsulfate (SLS, CH3(CH2)11SO4Na), Na2SO4, MgSO4, MgCl2, and NaCl were all brought from Sigma-Aldrich. All solvents used in this work were of high purity acquired from Sigma-Aldrich. Other chemicals in the present study were of analytical grade utilized as it is without any further purification.
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