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2 protocols using vinylsulfonic acid vsa

1

Dual-responsive Superparamagnetic Hydrogel Nanocomposites

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Synthesis of dual-responsive
superparamagnetic hydrogel nanocomposites, AA-VSA-P/SPIONs, with different
concentration of SPIONs (Fe3O4) was conducted
using acrylic acid (AA) (Sigma-Aldrich), vinylsulfonic acid (VSA)
(Sigma-Aldrich) monomers, benzoyl peroxide (BPO) (Himedia) initiator,
and ethylene glycol dimethacrylate (EGDMA) (Alfa Aesar) cross-linker
along with synthesized SPIONs. To synthesize SPIONs, iron(II) chloride
tetrahydrate (FeCl2·4H2O) (Sigma-Aldrich)
and iron(III) chloride hexahydrate (FeCl3·6H2O) (Sigma-Aldrich) were used. The study on dye adsorption properties
of the superparamagnetic hydrogels, AA-VSA-P/SPIONs, was carried out
using methylene blue (MB) dye (Sigma-Aldrich). The required aqueous
solutions were prepared with deionized water, whereas the pH of aqueous
solutions was maintained by adding suitable amounts of HCl (0.05 M)
or NaOH (0.05 M) solutions (Merck).
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2

Magnetic Hydrogel Synthesis with Acrylic Acid and Vinylsulfonic Acid

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The poly(acrylic acid-co-vinylsulfonic acid) magnetic hydrogel was prepared using
acrylic acid (AA) (Sigma-Aldrich) and vinylsulfonic acid (VSA) (Sigma-Aldrich)
as monomers, along with benzoyl peroxide (BPO) (HiMedia) and ethylene
glycol dimethacrylate (EGDMA) (Alfa Aesar) as an initiator and a cross-linker,
respectively. For Fe3O4 nanoparticle synthesis,
iron(II) chloride tetrahydrate (FeCl2·4H2O) (Sigma-Aldrich) and iron(III) chloride (FeCl3·6H2O) (Sigma-Aldrich) were used. The required aqueous solutions
were prepared with deionized water, and the pH of aqueous solutions
was maintained by adding appropriate amounts of HCl (0.05 M) or NaOH
(0.05 M) solutions (Merck).
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