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Nitrosyl tetrafluoroborate

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Nitrosyl tetrafluoroborate is a chemical compound used in various laboratory applications. It functions as a nitrosating agent, which can be utilized in organic synthesis reactions. The compound's core function is to facilitate the introduction of nitro groups into organic molecules.

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Lab products found in correlation

Oleic acid, by Merck Group (3 mentions) Sodium hydroxide (naoh), by Merck Group (2 mentions) 1 octadecene, by Merck Group (2 mentions) N n dimethylformamide (dmf), by Merck Group (2 mentions) Ammonium fluoride, by Merck Group (2 mentions) Antimony, by Merck Group (1 mentions) Phosphotungstic acid hydrate, by Merck Group (1 mentions) Phosphomolybdic acid hydrate, by Merck Group (1 mentions) Oleylamine, by Thermo Fisher Scientific (1 mentions) N methylformamide, by Merck Group (1 mentions) 1 2 ethanedithiol, by Merck Group (1 mentions) N hexane, by Merck Group (1 mentions) Absolute ethanol, by Merck Group (1 mentions) Ytterbium chloride hexahydrate, by Merck Group (1 mentions) Hexane, by Thermo Fisher Scientific (1 mentions) Methanol, by Thermo Fisher Scientific (1 mentions) Yttrium 3 chloride hexahydrate, by Merck Group (1 mentions) Neodymium 3 chloride hexahydrate, by Merck Group (1 mentions) Thulium chloride hexahydrate, by Merck Group (1 mentions) Anhydrous dichloromethane, by Merck Group (1 mentions)

Close spelling variants of this product

Nitrosyl tetrafluoroborate (NOBF4) (3 citations)

5 protocols using nitrosyl tetrafluoroborate

1

Synthesis of Inorganic Perovskite Materials

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Metallic granular tin (Sn, 99.5+%), antimony (III) oxide (Sb2O3, 99%), N-methylformamide (HCONHCH3, 99%), antimony(III) chloride (SbCl3, ≥99.0%), antimony(III) bromide (SbBr3, 99.99%), antimony(III) iodide (SbI3, 98%), zinc chloride (ZnCl2, ≥98%), iron(II) chloride (FeCl2, 98%), methylammonium bromide (CH6BrN, ≥99%, anhydrous), lead(II) bromide (PbBr2, 99.999%), cobalt(II) chloride (CoCl2, ≥98.0%), phosphotungstic acid hydrate (H3[P(W3O10)4]·xH2O (HPW), reagent grade), phosphomolybdic acid hydrate (H3[P(Mo3O10)4]·xH2O (HPMO), ACS reagent), indium triiodide (InI3, anhydrous, 99.998%), 4-(Hydroxymethyl)benzoic acid (HOCH2C6H4CO2H, 99%, BNZ), nitrosyl tetrafluoroborate (NOBF4, 95%), and 1,2-ethanedithiol (HSCH2CH2SH, ≥98.0% (GC)) were received from Sigma-Aldrich (Merck KGaA, Darmstadt, Germany). Oleylamine (OA, CH3(CH2)7CH = CH(CH2)8NH2, 80–90% of C18 chains) was bought from Acros Organics (Fisher Scientific GmbH, Schwerte, Germany). Absolute ethanol (ACS grade), nitric acid (ACS grade), n-hexane, tetrachlorethylene (TCE), and toluene were supplied by Merck (Merck KGaA, Darmstadt, Germany, Alfa Aesar, (Thermo Fisher (Kandel) GmbH, Kandel, Germany) and VWR Chemicals, (VWR International GmbH, Darmstadt, Germany) respectively.
Balitskii O., Mashkov O., Barabash A., Rehm V., Afify H.A., Li N., Hammer M.S., Brabec C.J., Eigen A., Halik M., Yarema O., Yarema M., Wood V., Stifter D, & Heiss W. (2022). Ligand Tuning of Localized Surface Plasmon Resonances in Antimony-Doped Tin Oxide Nanocrystals. Nanomaterials, 12(19), 3469.
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2

Synthesis of Rare-Earth Nanoparticles

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Yttrium(III) chloride hexahydrate (YCl3·6H2O, 99.99%), Neodymium(III) chloride hexahydrate (NdCl3·6H2O, 99.9%), Ytterbium chloride hexahydrate (YbCl3·6H2O, 99.99%), Thulium chloride hexahydrate (TmCl3·6H2O, 99.99%), Sodium hydroxide (NaOH, 98%), Ammonium fluoride (NH4F, 98%), ICG, nitrosyl tetrafluoroborate (NOBF4, 95%), N,N-dimethylformamide (DMF, anhydrous, 99.8%), 1-octadecene (90%), and oleic acid (OA, 90%) were all purchased from Sigma-Aldrich. Hexane (ACS reagent grade, ≥98.5%) and methanol (ACS reagent grade, ≥99.8%) were purchased from Fisher Scientific. Ethanol was provided by Decon Labs, Inc. The two photon dye AF-350 was donated by the U.S. Air Force Research Lab. All the chemicals were used without further purification.
Wang D., Wei W., Singh A., He G.S., Kannan R., Tan L.S., Chen G., Prasad P.N, & Xia J. (2017). Nonlinear Photoacoustic Imaging by in situ Multiphoton Upconversion and Energy Transfer. ACS photonics, 4(11), 2699-2705.
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3

Synthesis and Characterization of Functionalized Aryldiazonium Salts

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Nickel(II) acetylacetonate [Ni(C5H7O2)2], anhydrous tert‐butanol [(CH3)3COH], potassium hydroxide (KOH), 4‐nitrobenzenediazonium tetrafluoroborate (C6H4N3O2BF4), 3,5‐dichlorophenyldiazonium tetrafluoroborate (C6H3Cl2N2BF4), 4‐methoxybenzenediazonium tetrafluoroborate (CH3OC6H4N2BF4), 2,3,4,5,6‐pentafluoroaniline (C6F5NH2), nitrosyl tetrafluoroborate (NOBF4), anhydrous acetone (CH3COCH3), anhydrous dichloromethane (CH2Cl2), and acetonitrile‐d3(CD3CN) were purchased from Sigma‐Aldrich. 4‐carboxylbenzenediazonium tetrafluoroborate (CO2HC6H4N2BF4) was purchased from Chemtronica AB (Sweden). The water used for electrolyte solutions was deionized using a Millipore Milli‐Q UF Plus system (15–18 MΩ‐cm resistivity).
Fan L., Zhang B., Qiu Z., Dharanipragada N.V., Timmer B.J., Zhang F., Sheng X., Liu T., Meng Q., Inge A.K., Edvinsson T, & Sun L. (2020). Molecular Functionalization of NiO Nanocatalyst for Enhanced Water Oxidation by Electronic Structure Engineering. Chemsuschem, 13(22), 5901-5909.
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4

Synthesis and Characterization of Rare-Earth Nanoparticles

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Neodymium(III) acetate hydrate (99.9%), yttrium(III) acetate hydrate (99.9%), ytterbium(III) acetate hydrate (99.9%), thulium(III) acetate hydrate (99.95%), oleic acid (OA, 90%), 1-octadecene (ODE, 90%), sodium hydroxide (NaOH, ≥98%), ammonium fluoride (NH4F, ≥99.9%), ethanol (absolute), methanol (≥99.8%), cyclohexane (≥99%), tetrahydrofuran (THF, ≥99.9%), dopamine hydrochloride (≥99.9%), hydrochloric acid (HCl, 37%), dimethyl sulfoxide (DMSO, ≥99.9%), hydroxylamine hydrochloride (HH, 99%), N,N-dimethylformamide anhydrous (DMF, ≥99.8%), nitrosyl tetrafluoroborate (NOBF4 ≥ 95%), and PAA solution (Mw = 2000 g/mol) were purchased from Sigma-Aldrich, St. Louis, MO, USA. HEPES buffer (1 M) was purchased from Gibco. N-succinimidyl S-acetylthioacetate (SATA), sulfosuccinimidyl 4-(N-maleimidomethyl) cyclohexane-1-carboxylate (sulfo-SMCC), and CD133 (Prominin-1) monoclonal antibody (12-1338-42) was purchased from Thermo Fisher Scientific, Waltham, MA, USA. An Amicon Ultra centrifugal filter (0.5 mL, 30 K, 5 K) was purchased from Millipore (Bedford, MA, USA). Anti-EGFR antibody (ab40815), goat anti-rabbit IgG-H&L Alexa Fluor 488 (ab150077), and goat anti-rabbit IgG H&L Alexa Fluor 647 (ab150079) were purchased from Abcam, UK. A DAPI mounting kit was purchased from Vector Laboratories, Inc., Burlingame, CA, USA.
Kang D., Kim H.S., Han S., Lee Y., Kim Y.P., Lee D.Y, & Lee J. (2023). A local water molecular-heating strategy for near-infrared long-lifetime imaging-guided photothermal therapy of glioblastoma. Nature Communications, 14, 2755.
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5

Synthesis and Characterization of UCNPs

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Lanthanide chlorides with high purity (99.99%) were used for the synthesis of the UCNP. Sodium oleate (82%), oleic acid (90%, technical grade), octadecene (90%, technical grade), hexadecyltrimethylammonium bromide (CTAB, 98%), citric acid (99.5%), diethylene glycol (DEG, 99%), N,N-dimethyl formamide (DMF, 99.5%), nitrosyl tetrafluoroborate (95%), polyacrylic acid (MW = 1800 Da), trisodium citrate dihydrate (95%), tetraethyl orthosilicate for synthesis (98%), and ammonia solution (25% wt% in water) were obtained from Sigma Aldrich (Germany) and used without further purification. ICP standard solutions (1000 mg/L in nitric acid) used for calibration of the measurements quantifying fluoride and lanthanide ions were purchased from Sigma Aldrich. Dulbecco’s Modified Eagle Medium (DMEM) (product number: D5546) was purchased from Sigma Aldrich. The detailed composition of DMEM can be found in the supplementary information (Table S2, SI). All solvents employed for the optical measurements were purchased from Sigma Aldrich in spectroscopic grade. Water refers here to Milli-Q water.
Saleh M.I., Rühle B., Wang S., Radnik J., You Y, & Resch-Genger U. (2020). Assessing the protective effects of different surface coatings on NaYF4:Yb3+, Er3+ upconverting nanoparticles in buffer and DMEM. Scientific Reports, 10, 19318.
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