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3 protocols using 1 4 benzenedicarboxylic acid

1

Facile Synthesis of Metal-Organic Frameworks

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Co(CH3COO)2·4H2O, Ni(CH3COO)2·4H2O, 4,4′-biphenyldicarboxylic acid (H2BPDC), 2,6-naphthalenedicarboxylic acid (H2NDC), 1,4-benzenedicarboxylic acid (H2BDC), KOH, NaOH, KCl, ascorbic acid (AA), uric acid (UA), dopamine (DA), glucose, Ethanol, and N,N-Dimethylformamide (DMF) were bought from Sinopharm Chemical Reagent (Shanghai, China). Pure water (15 MΩ) used in the experiments was supplied by a Millipore System (Milli Q). Human serum was provided by the Second Affiliated Hospital of Hubei University of Science and Technology.
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2

Synthesis and Characterization of Metal-Organic Frameworks

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Copper nitrate trihydrate (Cu(NO3)2·3H2O, 99%), 1,4-benzenedicarboxylic acid (H2BDC, 98%), sodium nitrate (NaNO3, 99%), sodium nitrite (NaNO2, 99%), ammonium chloride (NH4Cl, 99%), sodium sulfate (Na2SO4, 99%), acetylene black, acetonitrile (CH3CN, 99%), NaOH (96%), HCl (36-38%), N, N-dimethylformamide (DMF, 99.5%), sulfamic acid, p-aminobenzenesulfonamide, N-(1-Naphthyl) ethylenediamine dihydrochloride, phosphoric acid, trichloromethane (CHCl3, 99%), and Nessler's reagent are from Sinopharm Chemical Reagent Co. Ltd. LiF (98.5%, 325 mesh, Alfa Aesar), Ti3AlC2 (98%, 400 mesh, 11 Technology Co. Ltd.), and all reagents were of analytical grade, and solutions were prepared by using ultrapure water (specific resistance of 18 MΩ cm).
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3

Synthesis of Metal-Organic Framework Catalysts

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Nickel(ii) nitrate hexahydrate (Ni(NO3)2·6H2O, 98%), cobalt(ii) nitrate hexahydrate (Co(NO3)2·6H2O, 98.5%), 1,4-benzenedicarboxylic acid (H2BDC, 99%), 4,4′-bipyridine (4,4′-bipy, 98%), sodium hydroxide (NaOH, 96%) were purchased from Sinopharm Chemical Reagent Co. Ltd (Shanghai, China). Commercial iridium oxide (IrO2, 99.9%) was purchased from Aladdin (Shanghai, China). Nafion (5 wt%) was purchased from Sigma-Aldrich (Beijing, China). The water for experiments was deionized (DI) water (18 MΩ). Other chemicals and solvents used in this work were obtained from commercial suppliers and used without further purification.
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