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2 protocols using k2co3

1

Synthesis of m-carborane-1-thiol derivatives

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Methyl 2-acetamidoacrylate, m-carborane-1-thiol, benzene-d6, methanol-d4 anhydrous diethyl ether, n-butyl alcohol, and Aliquat 336 were purchased from Sigma Aldrich (St. Louis, MO). Toluene, n-propyl alcohol and Na2SO4 were purchased from Fisher Scientific (Waltham, MA) and K2CO3 was purchased from VWR (Radnor, PA). Ethanol (200 proof) and isopropyl alcohol were purchased from Pharmco Aaper (Brookfield, CT). All the solvents were used as received without further purification.
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2

Synthesis of Functionalized Polymer Precursors

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1-Methylpiperidine (99%),
CH3I (99%), m-terphenyl (99%), trifluoromethanesulfonic
acid (98%), N,N-diisopropylethylamine
(DIPEA, 99%), N-methyl-4-piperidone (97%), and poly(vinyl
benzyl chloride) (PVBC) were purchased from Sigma-Aldrich. K2CO3 (99%), NaCl (99.5%), KOH (99.5%), NaNO3 (99%), AgNO3 (99%), dichloromethane (DCM, 99%), and dimethyl
sulfoxide (DMSO, 99.8%) were obtained from VWR Chemicals. Ultrapure
water was used throughout the experiments.
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