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7 protocols using sodium dodecylbenzenesulfonate sdbs

1

Synthesis and Characterization of Labeled Chemical Agents

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VX, GB, and HD* (13C labeled)
were obtained locally at the IIBR (>99% purity). PVA average MW
22
and 49 kDa were purchased from Fluka, PVA average MW 130 kDa, CEES,
sodium perborate monohydrate, sodium tetraborate decahydrate (borax),
TAED, sodium dodecylbenzenesulfonate (SDBS) and all solvents (HPLC
grade) were purchased from Sigma-Aldrich and used without further
purification. SPE (solid-phase extraction) NEXUS (Agilent) tubes of
6 mL (filled with 200 mg of sorbent) and 3 mL (filled with 60 mg of
sorbent) were used for GB collection in the wind tunnel. Polyethylene-backed
sorbent pad (Ultraclean BluePoly-backed-Gray Maintenance, 1UCGRL-PLY)
was purchased from Evolution Sorbent Products, LLC.
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2

Carbon Nanotube Characterization and Preparation

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In this study, two different types of CNTs are used. Multi-wall CNTs (MWCNTs) in powder form under the brand name of Nanocyl were provided by (Nanocyl). The CNTs had an average diameter of 9.5 nm, an average length of 1.5 µm, carbon purity of 90%, and a transition metal oxide < 1%. Single-wall CNTs (SWCNTs), also in powder form, were provided by (OCSiAl). The product name is TUBALL, with the specific characteristics of an average diameter of 1.8 ± 0.4 nm, length > 5 µm, carbon content > 85 wt.%, and metal impurities < 15 wt.%. Sodium dodecylbenzene sulfonate (SDBS), an anionic surfactant, was purchased from (Sigma Aldrich, St. Louis, MO, USA). Polyethyleneimine (PEI) solution ~50% in H2O (Mr 600,000–1,000,000) was also purchased from (Sigma Aldrich). All chemical reagents are used as received.
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3

Microplastic Removal from Water

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AlCl3·6H2O and FeCl3·6H2O as coagulants, anionic surfactant sodium dodecyl benzenesulfonate (SDBS), hydrochloric acid, sodium hydroxide, humic acid, sodium chloride and ethanol were obtained from Sigma-Aldrich (Saint Louis, MO, USA). The tap water used in the study was tap water from Rzeszow. The water parameters are presented in Table 1. The filters were obtained from Whatman glass microfiber-(GF/A; diameter—47 mm, pore size—1.6 µm).
Three commercially available types of PE and three PVC microplastics were purchased from Sigma-Aldrich (USA). Information on the microplastics tested is presented in Table 2.
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4

Thermal-Regulating Microcapsule Composites

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PCM microcapsules MPCM32D (composition: 17.4% melamine resin, 79.6% paraffin wax, water ≤ 3%) in a dry white powder were purchased from Microtek Laboratories Inc., Dayton, OH, USA. Multiwall carbon nanotubes NC7000 (average diameter: 9.5 × 10−9 m, average length: 1.5 μm) in form of 3 wt.% waterborne dispersion called Aquacyl AQ0302 were obtained from Nanocyl S.A., Sambreville, Belgium. Poly(3,4-ethylenedioxythiophene) poly(styrene sulfonate) (PEDOT: PSS) (1.3 wt.% dispersion in water, conductive grade), poly(diallyldimethylammonium chloride) (20 wt.% in water), sodium dodecylbenzenesulfonate (SDBS) and ethanol (95% denatured) were purchased from Sigma-Aldrich, Taufkirchen, Germany. Aqueous synthetic dispersion based on polyurethane (PU) Tubicoat MP and acrylic resin binder Itobinder PCM were obtained, respectively, from CHT Germany GmbH, Tübingen, DE and LJ Specialties Ltd., Chesterfield, Derbyshire UK.
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5

Fabrication of Graphene-SWCNT Epoxy Composites

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The PFs (approximately 1 mm thickness) were obtained from Superbond Co., Korea. The SWCNTs (diameter of 5 nm and length of 10–20 µm) were obtained from Nanosolution Co., Korea. Graphite powder (particle size of ≤ 5 μm), sulfuric acid (H2SO4, 98%), phosphoric acid (H3PO4, 85%), potassium permanganate (KMnO4), hydrogen peroxide (H2O2, 30%), hydrogen chloride (HCl, 36%), and sodium dodecyl benzenesulfonate (SDBS) were purchased from Sigma-Aldrich Co., USA. The polymeric matrix system comprised an epoxy resin (diglycidyl ether of bisphenol A, YD-128) obtained from Kukdo Chemical Co., Korea, and a hardener (4,4'-diaminodiphenylmethane, DDM) obtained from Sigma-Aldrich Co., USA.
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6

Analytical Standards of Triazole Fungicides

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All chromatography-grade solvents including acetonitrile, methanol, ethanol and propanol were purchased from Merck KGaA, Germany. Sodium dodecyl sulfate (SDS) was obtained from Merck Schuchardt OHG, Germany. Cetyltrimethylammonium bromide (CTAB) and sodium dodecylbenzene sulfonate (SDBS) were obtained from Sigma-Aldrich, Germany. The analytical standards of triazole including myclobutanil, triadimefon, tebuconazole, hexaconazole and diniconazole were purchased from Dr Ehren-storfer GmbH, Germany. Stock standard solution of each triazole fungicide (1000 μg mL−1) was prepared by dissolving an appropriate amount in methanol and stored at 4 °C. Working standard solutions was prepared by diluting the stock standard solution with water. Deionized water (Millipore Waters, USA) with the resistivity of 18.2 MΩ cm was used throughout the experiments.
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7

Emulsion Copolymerization for Leather Finishing

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The monomers, butyl acrylate (BA, ≥99.0%), methyl methacrylate (MMA, ≥98.5%), glycidyl methacrylate (GMA, ≥97%), and acrylonitrile (AN, ≥99.0%) were purchased from Sigma-Aldrich, Schnelldorf, Germany and used in emulsion copolymerization. Sodium dodecyl benzene sulfonate (SDBS, Sigma-Aldrich, Steinheim, Germany), sodium bicarbonate (NaHCO3, Sigma-Aldrich, Steinheim, Germany), potassium persulfate (KPS, Sigma-Aldrich, Steinheim, Germany) were used as an emulsifier, a buffer agent and an initiator, respectively. All chemicals were used as received without any further purification. Ultrapure water was used as a solvent to perform the reactions. The syntheses took place in a four-neck round-bottom 250 mL glass reactor equipped with a condenser, nitrogen inlet, monomer dropping funnel, and initiator solution dropping funnel. For the reactions, a Heidolph (Schwabach, Germany) magnetic stirrer with a temperature control probe was used to heat the reactor in an oil bath.
Cattle crust leather suitable for footwear, gifted from Sepiciler Co. (İzmir, Turkey), was used for finishing applications. The other necessary finishing chemicals, combined with the synthesized copolymer emulsions such as wax emulsion, black pigment, nitrocellulose lacquer emulsion, and silicon-based touch modifier, were obtained from Stahl Co. (Waalwijk, The Netherlands).
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