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2 protocols using trioctylphosphine top

1

Synthesis of Pd/C and Ni Catalysts

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Palladium (II) acetylacetonate (Pd(acac)2, 99%), nickel (II) acetylacetonate (Ni(acac)2, 95%), trioctylphosphine (TOP) (90%), Nafion solution (5 wt%), Palladium on activated carbon (Pd/C, 10 wt%) were purchased from Alfa Aesar. Oleylamine (OAm) (>70%) was purchased from Sigma Aldrich. NaOH, ethanol, cyclohexane, toluene, n-hexane and isopropanol were obtained from Beijing Chemical Reagent Company. Ketjen Black was obtained from Shanghai HESEN Electric Company. Milli-Q ultrapure water was utilized through all the experiments.
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2

Synthesis and Characterization of Colloidal Nanocrystals

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Octadecene (ODE) (Sigma-Aldrich, 90%), cadmium acetate anhydrous (Cd(Ac)2) (Sigma-Aldrich, 99.995%), cadmium oxide (CdO) (Strem Chemicals, 99.99%), myristic acid (Sigma-Aldrich, 99%), selenium powder (Se) (Strem Chemicals, 99.99%), sulphur powder (S) (Sigma, 99.99%), oleic acid (OA) (Sigma-Aldrich, 90%), ethanethiol (Fluka, >98%), butanethiol (Aldrich-Chemistry, 99%), octanethiol (Fluka, >97%), dodecanethiol (Aldrich-Chemistry, >98%), octadecanethiol (Aldrich-Chemistry, 98%), trioctylphosphine (TOP) (Alfa Aesar, 90%), tributylphosphine (TBP) (Cytec, Solvay), cadmium chloride hydrate (CdCl2•xH2O) (Sigma-Aldrich, 99.995%), cadmium iodide hydrate (CdI2•xH2O) (Aldrich-Chemistry, 99%), sodium tetrahydroborate (NaBH4) (Sigma, 99%), sodium sulphide nonahydrate (Na2S•9H2O) (Aldrich-Chemistry , >99.99%), toluene (VWR, 99.5%), n-hexane (VWR, 99%), ethanol (VWR, 96%), methanol (Carlo Erba, 99.9%), N-methylformamide (NMF) (Carlo Erba, 99%), ammonia solution (28%, Aldrich-Chemistry)
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