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2 protocols using sodium bromate

1

Synthesis and Characterization of Liquid Crystals

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Decylaniline
(10C) was purchased
from Alfa Aesar. Sodium nitrite (NaNO2), sodium bromide
(NaBr), sodium bromate (NaBrO3), magnesium chloride (MgCl2), calcium chloride (CaCl2), iron(III) chloride
(FeCl3), and zinc(II) chloride (ZnCl2) were
purchased from Sigma-Aldrich. Potassium carbonate (K2CO3) was purchased from J.T. Baker. Potassium phosphate tribasic
(K3PO4) was purchased from Acros. Nematic liquid-crystal
4-cyano-4′-pentylbiphenyl (5CB) was purchased from Tokyo Chemical
Industry. 4-(Decyloxy)aniline (10CO) and decyl 4-aminobenzoate (10CBA)
were synthesized following the previous reports and identified through
the 1H NMR spectrum collected in the Supporting Information.56 (link),57 (link) Deionized water was
obtained from a Milli-Q system (Millipore). Real water samples, i.e.,
tap water and pond water, were collected in the campus of Tamkang
University. A Bruker AC-300 FT-NMR spectrometer was used to record
the NMR spectra.
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2

Photocrosslinkable Hydrogel Synthesis

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N-Isopropyl acrylamide (NIPAAm, ≥99%), N,N′-methylenebisacrylamide (BIS, 99%), potassium persulfate (KPS, ≥98%), sodium bromate (NaBrO3, 99%), tris(2,2′-bipyridyl) dichlororuthenium(ii) hexahydrate (99.95%), acrylic acid (AAc, 98%), 1-decanol (99%), methanol (anhydrous, >99.8%), 2-hydroxyethyl methacrylate (HEMA, 98%), 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide (EDC), sorbitan monooleate (Span 80), N,N,N′,N′-tetramethyl ethylenediamine (TEMED, ≥99.5%) and 2,2′-azobis(2-methyl propionitrile) (AIBN, 98%) were all from Sigma-Aldrich. 4-Vinyl-4′-methyl-2,2′-bipyridine (99%) was ordered from Ark Pharm, Inc. Ruthenium(ii) (4-vinyl-4′-methyl-2,2′-bipyridine) bis(2,2′-bipyridine) bis(hexafluoro phosphate) (noted Ru(bpy)3 monomer as below) was synthesized according to the previous literature with minor modifications.34–39 (link) All chemicals were used as received. Double distilled water was ordered from WaterLab Solutions and was a reverse osmosis product according to the information from the vendor.
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