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3 protocols using hocl3 6h2o

1

Synthesis of Lanthanide-Doped Nanoparticles

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ErCl3·6H2O (99.9%), YCl3·6H2O (99.9%), YbCl3·6H2O (99.9%), TmCl3·6H2O (99.9%), HoCl3·6H2O (99.9%), NaOH (98+%), NH4F (98+%), 1-octadecene (ODE) (90%), oleic acid (OA) (90%), Igepal CO-520, NH3·H2O (30 wt%), and tetraethyl orthosilicate (TEOS) (99.0+%) were purchased from Sigma-Aldrich. All chemicals were used as received without further purification.
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2

Lanthanide Salt Solutions Preparation

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Stock solutions (5 g/L as salt concentration) were prepared from the following Lanthanide salts: LaCl3-7H2O, CeCl3-7H2O, Pr(NO3)3-6H2O, Nd(NO3)3-6H2O, Sm(NO3)3-6H2O, EuCl3-6H2O, GdCl3-6H2O, TbCl3-6H2O, Dy(NO3)3-6H2O, HoCl3-6H2O, Er(NO3)3-5H2O, Tm(NO3)3-5H2O, YbCl3-6H2O, and LuCl3-6H2O, purchased from Sigma Aldrich, St. Louis, Missouri U.S.A. The purity of all salts was about 99.9 %. Two days prior to experiments, exposure concentrations were obtained by diluting the stock solutions in ultrapure water and stored at 4 °C.
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3

Synthesis of Phenol-Based Lanthanide Complexes

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Solvents and other general reagents used in this work were purified according to the standard procedures. 29 2,6-Bis(hydroxymethyl)-4-methylphenol, activated manganese(IV)dioxide (MnO 2 ), DyCl 3 •6H 2 O, TbCl 3 •6H 2 O and HoCl 3 •6H 2 O were obtained from Sigma Aldrich Chemical Co. and were used as received. Acetyl hydrazide and 2-(hydroxymethyl)-6-carbaldehyde-4-methylphenol were prepared according to the literature procedure. 23e Hydrazine hydrate (80%), pivalic acid and sodium sulphate (anhydrous) were obtained from S.D. Fine Chemicals, Mumbai, India and were used as such.
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