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9 protocols using iron 0 pentacarbonyl

1

Fabrication of Nanomaterials with AAO

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Iron (0) pentacarbonyl (>99%), ammonium persulfate (>98.0%), aq. HCl (>37%), sodium hydroxide (>98%), N-methyl-2-pyrrolidone (NMP) (anhydrous 99.5%), and aniline (>99%) were purchased from Sigma-Aldrich (Yongin, Korea). Anodic aluminum oxide (AAO) (Whatman® Anodisc 47, 47 mm diameter, 60 µm thickness, and 200 nm pore size) was purchased from Merck (Seoul, Korea).
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2

Synthesis of Magnetic Nanoparticles

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Iron(0)pentacarbonyl (Fe(CO)5, liquid 99.99%), 1-octadecene (ODE, technical grade 90%), oleic acid (OLEA, technical grade 90%), oleylamine (technical grade 70%), 1,2-dodecanediol (DDIOL, technical grade 90%), dopamine hydrochloride ((HO)2C6H3CH2CH2NH2HCl, powder), copper(II) sulfate pentahydrate (CuSO4•5H2O, powder), low metal trace 70% nitric acid and phosphotungstic acid solution (10% w/v) were purchased from Sigma-Aldrich and used as received. All solvents, namely chloroform, hexane, isopropanol and acetone, were also purchased from Sigma-Aldrich and were of the highest purity available. Phosphate-buffered saline (PBS), tris(hydroxymethyl) aminomethane hydrochloride (Tris-HCl) and borate buffers were prepared by using reagent-grade salts purchased from Sigma. All aqueous solutions were prepared by using water obtained from a Milli-Q Gradient A-10 system (18.2 MΩ cm, organic carbon content ≤ 4 µg L−1, Merck Millipore, Darmstadt, Germany).
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3

Synthesis of Iron Nanoparticles

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Iron(0)pentacarbonyl
(Fe(CO)5,
99,99% trace metal basis), oleic acid (OA, ≥ 93% technical
grade), and dioctyl ether (Oct2O, > 99%) were purchased
from Sigma-Aldrich; ethanol (EtOH > 96% technical grade) and toluene
(≥95% Rotipuran) were obtained from Carl Roth.
All chemicals
were used as received without further purification.
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4

Synthesis and Characterization of Iron-Loaded Lipid Nanoparticles

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Oleic acid (OA, >99.9%), octyl ether (99%), iron (0)-pentacarbonyl (Fe(CO)5, > 99.99%), hydrocaffeic acid (HCA, 98%), tetrahydrofuran (THF, anhydrous, >99.9%), dimethyl sulfoxide (DMSO, > 99.5%), and cholesterol (>99%) were purchased from Sigma Aldrich (Dorset, UK). Nitric acid (65% HNO3), hydrochloric acid (30% HCl), and hydrogen peroxide (30% H2O2) were obtained from Merck Millipore (Milford, MA, USA). Standard solution of Fe (1000 µg Fe/mL in 2–3% HNO3) was obtained from Merck (Darmstadt, Germany). 1,2-dioleoyl-sn-glycero-3-phosphatidylcholine (DOPC), 1,2-dipalmitoyl-sn-glycero-3-phosphatidylcholine (DPPC), 1,2-distearoyl-sn-glycero-3-phophatidylcholine (DSPC), and N-[carbonyl-methoxy(polyethylene glycol)-2000]-1,2-distearoyl-sn-glycero-3-phosphoethanolamine, sodium salt (DSPE-PEG2000) were a kind gift from Lipoid GmbH (Ludwigshafen, Germany).
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5

Synthesis of Metal Nanoparticles

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Reagents Platinum(II) acetylacetonate (Pt(acac) 2 , 98% ABCR, stored in glovebox), iron(0) pentacarbonyl (Fe(CO) 5 , 99.99% Sigma Aldrich, stored in fridge inside glovebox), hydrazine monohydrate (N 2 H 4 •H 2 O, 98% Sigma Aldrich), 1-octadecene (ODE, 90% Sigma Aldrich), oleic acid (90% Sigma Aldrich, stored in fridge), oleylamine (90% Sigma Aldrich), benzyl ether (98% Sigma Aldrich), 1,2-hexadecanediol (98% Sigma Aldrich), 1-adamantanecarboxylic acid (99% Sigma Aldrich), diphenyl ether (99% Acros), 1,2-dichlorobenzene (99% Sigma Aldrich, stored in Glovebox), hexadecylamine (HDA, ≥94% Merck), cobalt carbonyl (Co 2 (CO) 8 , ≥90% moisted with 1-10% n-hexane Sigma Aldrich, stored in fridge inside glovebox), isopropanol (≥99.8% Sigma Aldrich), n-hexane (≥99% Honeywell), acetone (≥99.5% Sigma Aldrich), ethanol (≥99.9% Sigma Aldrich), toluene (≥99.7% Sigma Aldrich), dried acetone (dried over molecular sieves 3 Å, distilled and stored in glovebox), hydrochloric acid (≥37% Sigma Aldrich), nitric acid (trace ≥99.999% Sigma Aldrich), liquid CO 2 (Linde 30 kg with riser tube). These chemicals were used without further purification.
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6

Synthesis of metal nanoparticles using acetylacetonates

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Nickel(II) acetylacetonate (Ni(acac)2, 95%, Sigma-Aldrich), cobalt(II) acetylacetonate (Co(acac)2, 99%, Sigma-Aldrich), iron(III) acetylacetonate (Fe(acac)3, 97%, Sigma-Aldrich), iron(0) pentacarbonyl (Fe(CO)5, 99.99%, Sigma-Aldrich), dicobalt octylcarbonyl (Co2(CO)8, >90%, Sigma-Aldrich), tri-n-octylphosphine (TOP, (P(oct)3, 97% STREM), oleylamine (OAm, C18H37N, 70%, Sigma-Aldrich), octylether (C16H34O,
90%, TCI America), 1-octadecene (ODE, C18H36, 90% tech, Sigma-Aldrich), chloroform (CHCl3, 99%, Fisher
Scientific), ethanol (C2H5OH, 200 proof, Decon
Laboratories), and hexane (C6H14, >98.5%,
Fisher
Scientific) were used. Fe(CO)5, Co2(CO)8, TOP, and ODE were stored in a glovebox under argon. Oleylamine
was further dried over molecular sieves, while all other chemicals
were used as received.
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7

Synthesis of Iron-Oxide Nanoparticles

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Oleic acid 90%, hexadecylamine
(HDA) synthesis grade, iron(0) pentacarbonyl, 1-octanol synthesis
grade, formaldehyde 37 wt % in H2O, polyvinylpyrrolidone
powder (average Mw ∼ 55,000 g·mol–1), and K2CO3 were purchased
from Sigma-Aldrich (MERCK). (3-Aminopropyl)triethoxysilane 98% (APTES),
chloroform >99.8%, and hydrogen tetrachloroaurate(III) hydrate
99.9%
(HAuCl4) were purchased from Alfa Aesar. Absolute ethanol,
EPR Ph.Eur. ≥99.5% V/V, was purchased from Labbox.
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8

Iron Nanoparticle Synthesis via Thermal Decomposition

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Chemicals used for this study were iron (0) pentacarbonyl (Fe(CO)5, >99.99%), oleylamine (C18H35NH2, 80–90%), 1-octadecene (C18H36, 90%), trimethylamine N-oxide ((CH3)3NO, 98%), and hexane(CH3(CH2)4CH3, >95%), all obtained from Sigma-Aldrich (Burlington, MA, USA).
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9

Synthesis and Characterization of Nickel-Polycarbonate Composite Fibers

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Oleic Acid (99%), 1-Octanol (>98%), and iron (0) pentacarbonyl (>99.99% trace metals basis) except hexadecylamine, which has a technical grade (90%), were purchased from Sigma Aldrich. All reagents were used without further purification. Commercial Nickel particles (purity 0.998, average nominal size less than 1 μm) were purchased from Sigma Aldrich, Saint Louis, MO, USA. Corethane, a medical-grade polycarbonate (Corvita Corporation, Miami, FL, USA), was used to prepare electrospun fibers. Organic solvents, including tetrahydrofuran (THF) and dimethylformamide (DMF), as well as other chemicals, such as Polyethylene glycol (PEG, Mw 700Da), were purchased from Sigma Aldrich, Saint Louis, MO, USA.
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