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6 protocols using zinc acetate zn oac 2

1

Synthesis of Polymeric Materials

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Dimethyl 5-sodiosulfoisophthalate (Na-DMSI) (98.00%), 2-ethyl furoate (99.00%), hexane-1.6- diamine (HMD, 99 + % Fluka), ethylene glycol (EG) (99.80%), tetrabutoxytitanium Ti(OBu)4 (97.00%), zinc acetate (Zn(OAc)2) (99.99%), and sodium acetate (NaOAc) were purchased from Sigma-Aldrich.
All chemicals were used as received, without further purification.
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2

Aqueous Zinc Oxide Synthesis

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All solutions were prepared with reagent grade chemicals and deionized water (Milli-Q system). Zinc acetate (Zn(OAc)2) and sodium hydroxide (NaOH) were obtained from Sigma-Aldrich and VWR Chemicals (Leuven, Belgium), respectively. Monopotassium phosphate (KH2PO4) was procured from Sigma-Aldrich.
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3

Isosorbide-Based Photopolymerizable Hydrogel

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Isosorbide(I) (98%), vanillin(V) (99%), methacrylic
anhydride (MAA) (≥94%), 4-(dimethylamino)pyridine (DMAP) (≥99%),
phenylbis(2,4,6-trimethylbenzoyl)-phosphine oxide (BAPO) (97%), hydrochloric
acid (HCl) (37%), and zinc acetate (Zn(OAc)2) (99.99%)
were purchased from Sigma-Aldrich. 2,2′-(Ethylenedioxy)bis(ethylamine)
(Dom) (≥97%) and dichloromethane (DCM) (≥99%) were obtained
from Fisher Scientific and sodium bicarbonate (≥99.7%) from
Merck. Sodium hydroxide (NaOH) (99%), magnesium sulfate (MgSO4) (≥99%), acetone (≥99%), ethanol (EtOH) (100%),
and deuterated chloroform (CDCl3) (99.8 atom % D) were
received from VWR. All chemicals and solvents were used without any
additional purification.
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4

Synthesis of Quantum Dots and Photosensitizers

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Indium acetate (In(OAc)3, 99.99%, Sigma), zinc acetate (Zn(OAc)2, 99.99%, Sigma), copper iodide (CuI, 99.999%, Sigma), dodecanethiol (DDT, >98%, Sigma), oleylamine (OA, 70%, Sigma), 1-octadecene (ODE, 90%, Sigma), zinc oxide (ZnO, 99%, Alfa Aesar), disodium terephthalate (DST, 99+%, Alfa), nitrotetrazolium blue chloride (NBT, >98%, Sigma), leuco crystal violet (LCV, 99%, Sigma), enzyme horseradish peroxidase (HRP, type II, Sigma), singlet oxygen sensor green (SOSG, Molecular Probes), Rose Bengal (RB, 95%, Sigma) and chloroform (>99%, Carlo Erba) were used without further purification.
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5

Peptide and Protein Modification Reagents

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Methanol and glacial acetic acid were purchased from Mallinckrodt (Phillipsburg, NJ, USA). Sodium periodate, iodoethane, dimethylformamide (DMF), trifluoroacetic acid (TFA), n-propanol, zinc acetate (Zn(OAc)2), and trans,trans-farnesyl chloride were purchased from Sigma-Aldrich (St. Louis, MO, USA). RAKGCKGR was synthesized by CHI Scientific (Maynard, MA, USA). KGAILCGIALK was synthesized by CPC Scientific (Sunnyvale, CA, USA). A-factor was a generous gift from the Hrycyna Lab at Purdue University. The carbamidomethyl (cam)-modified BSA tryptic digest was purchased from ThermoFisher Scientific (Waltham, MA, USA). All peptide stock solutions for positive nanoelectrospray were prepared in a 49.5:49.5:1 (v/v/v) solution of Methanol/water/acetic acid at an initial concentration of ~1 mg/mL and diluted 100-fold prior to use. The solution of Sodium periodate (50:50 v/v Methanol/water) anions was prepared at a concentration of ~1 mg/mL and diluted 10-fold prior to use.
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6

Synthesis of Colloidal Nanocrystals

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All chemicals, indium acetate (In(OAc)3, 99.99% trace metal basis, Sigma-Aldrich, St. Louis, MO, USA), zinc acetate (Zn(OAc)2, 99.99%, Sigma-Aldrich), lauric acid (98%, Sigma-Aldrich), myristic acid (99%, Sigma-Aldrich), stearic acid (99%, Sigma-Aldrich), oleic acid (90% technical grade Sigma-Aldrich), gallium trichloride (GaCl3 beads, anhydrous 99.999% trace metals basis, Sigma-Aldrich), 1-hexanethiol (95%, Sigma-Aldrich), 1-octanethiol (≥98.5%, Sigma-Aldrich), 1-dodecanethiol (≥98%, Sigma-Aldrich), 1-octadecene (ODE, 90% technical grade, Sigma-Aldrich), and tris(trimethylsilyl)phosphine ((TMS)3P, 10 wt% in hexane, SK Chemicals, Gyeonggi-do, Korea), were used without any further purification.
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