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N trioctylphosphine

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N-trioctylphosphine is a chemical compound used in various laboratory applications. It is a colorless, viscous liquid with a high boiling point. N-trioctylphosphine is commonly utilized as a solvent, complexing agent, and stabilizer in scientific research and analysis.

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Lab products found in correlation

Selenium pellets, by Merck Group (2 mentions) Sulfur, by Thermo Fisher Scientific (2 mentions) Dioctylamine, by Merck Group (2 mentions) Zinc acetate, by Merck Group (2 mentions) 1 octadecene, by Thermo Fisher Scientific (2 mentions) Oleylamine, by Thermo Fisher Scientific (2 mentions) Ethanol, by Merck Group (2 mentions) Oleic acid, by Merck Group (2 mentions) Cadmium oxide, by Thermo Fisher Scientific (2 mentions) Quartz glass cuvettes, by Starna Cells (1 mentions) Trioctylphosphine oxide, by Merck Group (1 mentions) Myristic acid, by Merck Group (1 mentions) Hexane, by Thermo Fisher Scientific (1 mentions) Indium 3 acetate, by Merck Group (1 mentions) Indium 3 acetylacetonate, by Merck Group (1 mentions) Quartz cuvette, by Starna Cells (1 mentions) Myristic acid, by Thermo Fisher Scientific (1 mentions) 1 dodecanethiol, by Merck Group (1 mentions) Dichloromethane, by Merck Group (1 mentions) Ethylene glycol, by Merck Group (1 mentions)

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Trioctylphosphine (113 citations)

3 protocols using n trioctylphosphine

1

Synthesis of Colloidal Semiconductor Nanocrystals

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Oleylamine (OAm, 80–90%), 1-octadecene (ODE, 90%), diphenylphosphine (DPP, 98%), sulfur (S, 99.999%), tris(trimethylsilyl) phosphine (TMS3P, 98%), cadmium oxide (CdO, 99.95%) and hexanes (99%) were purchased from Fisher Scientific. Indium (III) acetate [In(Ac)3, 99.99%], oleic acid (OA, 90%), n-trioctylphosphine (TOP, 97%), selenium pellets (Se, 99.99%), zinc acetate [Zn(Ac)2, 99.0%], dioctylamine (98%), and ethanol (99.8%) were purchased from Sigma-Aldrich. ODE was heated to 120°C under vacuum for several hours prior to use and stored in an argon glovebox. All other chemicals were used directly without further purification. Quartz glass cuvettes were purchased from Starna Cells Inc. All air-sensitive materials were stored and handled in a glovebox under argon.
Toufanian R., Piryatinski A., Mahler A.H., Iyer R., Hollingsworth J.A, & Dennis A.M. (2018). Bandgap Engineering of Indium Phosphide-Based Core/Shell Heterostructures Through Shell Composition and Thickness. Frontiers in Chemistry, 6, 567.
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2

Synthesis of Colloidal Quantum Dots

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Oleylamine (OAm, technical grade, 70%), 1-octadecene (ODE, 90%), sulfur (S, 99.999%), and hexanes (99%) were purchased from Fisher Scientific. Tris(trimethylsilyl) phosphine ((TMS)3P, 98%) was purchased from Strem Chemical, Inc. Chloroform was purchased from J.T.Baker. Indium (III) acetate (In(Ac)3, 99.99%), oleic acid (OA, 90%), n-trioctylphosphine (TOP, 97%), selenium pellets (Se, 99.99%), zinc acetate (Zn(Ac)2, 99.0%), indium (III) acetylacetonate (In(Acac)3, 99.99%), trioctylphosphine oxide (TOPO, 99%), myristic acid (HMy, 99%), ethanol (99.8%), dioctylamine (97%), and InP/ZnS QDs (λem=670 nm) in toluene were purchased from Sigma-Aldrich. ODE was heated to 120 °C under vacuum for several hours with multiple argon backfill and evacuation cycles to ensure complete removal of air and water and stored in an argon glovebox prior to use. CdSe/ZnS QDs were purchased from NNCrystal US Corporation. All other chemicals were used directly without further purification. Quartz cuvettes were purchased from Starna Cells Inc. All air-sensitive materials were stored and handled in an argon glovebox.
Toufanian R., Chern M., Kong V.H, & Dennis A.M. (2021). Engineering Brightness Matched Indium Phosphide Quantum Dots. Chemistry of materials : a publication of the American Chemical Society, 33(6), 1964-1975.
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3

Synthesis of Colloidal Nanoparticles

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Zinc acetate (Zn(ac)2, 99.99%), sulphur (S, 99.99%), selenium (Se, 99.99%), oleic acid (OA, 99%) and 1-octadecene (ODE, 99%) were purchased from Uniam. n-Trioctylphosphine (TOP, technical grade, 90%), 1-dodecanethiol (DDT, 98%), ethylene glycol and dichloromethane (anhydrous, >99.8%) were purchased from Sigma Aldrich. Myristic acid (MA, 90%), cadmium oxide (CdO, 99.9%) were purchased from Alfa Aesar. 4-Azido-2,3,5,6-tetrafluorobenzoic acid (>98%) and triethyl amine (TEA, 99%) were purchased from TCI. All chemicals are used without further purification. Thionyl chloride and the rest of other solvents were purchased from Daejung and used as received.
Yang J., Hahm D., Kim K., Rhee S., Lee M., Kim S., Chang J.H., Park H.W., Lim J., Lee M., Kim H., Bang J., Ahn H., Cho J.H., Kwak J., Kim B., Lee C., Bae W.K, & Kang M.S. (2020). High-resolution patterning of colloidal quantum dots via non-destructive, light-driven ligand crosslinking. Nature Communications, 11, 2874.
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