Example 3
The test was conducted in accordance with the process flow shown in FIG. 3 using Feedstock oil C as a starting material for catalytic conversion on an equal-diameter riser reactor. Feedstock oil C was contacted with Catalyst C, and reacted in the riser reactor under conditions including a reaction temperature of 530° C., a reaction time of 3.5 seconds, a catalyst-to-oil weight ratio of 8, and a steam-to-oil weight ratio of 0.1 to obtain a spent catalyst and a reaction product. The spent catalyst was regenerated, and the regenerated catalyst was recycled to the riser reactor as the catalytic conversion catalyst. The reaction product was split according to distillation range in a product separation device to obtain dry gas, ethylene, propylene, propane, a fraction comprising C4 olefin (with a C4 olefin content of 85.0 wt %), butane, gasoline, diesel oil and slurry oil.
The fraction comprising C4 olefin was fed to an oligomerization reactor for oligomerization, and the fraction comprising C12 olefin (with a C12 olefin content of 85.3 wt %) separated by a rectifying column was recycled to the riser reactor. The C12 olefin recycled to the riser reactor for further cracking accounted for 14.17 wt % of the total catalytic conversion feedstock. The operating conditions and product distribution are listed in Table 5.
The operation was substantially the same as in Example 3, except that the catalytic conversion product was split according to distillation range in the product separation device to obtain dry gas, liquefied gas, propylene, gasoline, diesel oil and slurry oil, and the recycling of the catalytic conversion product was not performed. The operating conditions and product distribution are listed in Table 5.
TABLE 5
Operating conditions and results of
Example 3 and Comparative Example 3
Comparative
ItemExample 3Example 3
Feedstock oilCC
Operating conditions (catalytic conversion reaction device)
ReactorRiser reactorRiser reactor
CatalystCC
Reaction temperature, ° C.530530
Reaction time, second3.53.5
Steam/feedstock oil weight ratio0.10.1
Catalyst/feedstock oil weight ratio88
Operating conditions (oligomerization reactor)
CatalystE/
Temperature of C4 olefin200/
oligomerization, ° C.
Pressure of C4 olefin oligomerization,2/
MPa
Weight hourly space velocity of C41/
olefin oligomerization, h−1
Product distribution, wt %
Dry gas3.753.72
Methane0.890.87
Ethane0.680.66
Liquefied gas22.7523.10
Propylene13.858.56
Propylene/propane/5.3
Isobutene/isobutane/1.0
Gasoline43.7043.51
Diesel oil19.5519.49
Slurry oil3.533.51
Coke6.726.67
Total100.00100.00