The same reaction as that
described above for the general amination of hydrocarbons was conducted,
with the exception that a mixture of ethylbenzene and p-X-ethylbenzene (X = MeO, Me, F, I, Br, CF3, NO2) was present (0.125 mmol each). The nitrene source employed was
PhI = NTces (0.50 mmol). The reaction was allowed to run for 5 h and
was then flash chromatographed on silica gel with methylene chloride.
The solvent was then evaporated, and the residue was quantitatively
evaluated by using 1H NMR analysis (CDCl3).
described above for the general amination of hydrocarbons was conducted,
with the exception that a mixture of ethylbenzene and p-X-ethylbenzene (X = MeO, Me, F, I, Br, CF3, NO2) was present (0.125 mmol each). The nitrene source employed was
PhI = NTces (0.50 mmol). The reaction was allowed to run for 5 h and
was then flash chromatographed on silica gel with methylene chloride.
The solvent was then evaporated, and the residue was quantitatively
evaluated by using 1H NMR analysis (CDCl3).
