Poly(propylene oxide) (PPO) and the utilized solvents were acquired from Sigma Aldrich (now Merck), St. Louis, MO, USA. The chemical structure of the polymer is displayed in Scheme 1.
The polymer solutions were prepared by dissolving 2.5 g of PPO powder in 100 mL of each of the following solvents, acquired from Sigma Aldrich (now Merck): benzonitrile (anhydrous, ≥99%), carbon disulfide (anhydrous, ≥99%), chloroform (anhydrous, ≥99%, contained 0.5–1.0% ethanol as a stabilizer), ethyl acetate (anhydrous, ≥99.8%), and p-dioxane (anhydrous, ≥99.8%). The pH of the polymer solutions did not vary intentionally during experiments, and the small variations were caused by the combination of PPO (pH = 4) with the selected solvents having pH values comprised between 4 and 7.
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