Geochemical data for the January and June samples have been reported in other publications9 (link)19 (link). For the August samples, the same analytical procedures were used for water and sediment geochemical analyses. Cation and anion concentrations were measured by using ion chromatography (Dionex DX-600, USA), and DOC and TN concentrations were measured on a multi N/C 2100S analyzer (Analytik Jena, Germany). Sediment samples for TOC and mineralogy measurements were dried and ground. TOC samples were treated with 1 N HCl overnight to remove carbonates and then washed to a neutral pH followed by analysis with the multi N/C 2100S analyzer. Samples for quantitative mineralogy were X-ray scanned from 2 to 70 degree two theta with Cu K-alpha radiation (40 kV, 35 mA).
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