16.00 g P1000, 4.00 g CD-MDI, and 1.05 g polyurethane polyurea bilayer STF microcapsules were mixed and stirred for 2 min by a planetary stirrer. It was poured into a Teflon mold and cured at room temperature for 24 h, followed by curing in an oven at 60 °C for 24 h to give a 1 mm thick composite polyurea material (PM-STF-PUA). The preparation method of pure polyurea sample was consistent with the above method but the microcapsule addition amount was 0%.