In an NMR tube,
0.033 mL of iodobenzene (0.30 mmol, 1.0 equiv), 0.097 mL of tributylvinyltin
(0.33 mmol, 1.1 equiv), 5 mol % [Pd] catalyst, and 0.05 g of (0.03
mmol, 0.1 equiv) 1,3,5-trimethoxybenzene were dissolved in 1 mL dry,
degassed THF-d8. The reactions were carried
out in the dark and monitored every 2 h by 1H, 31P{1H}, and, when applicable, 19F NMR spectroscopy.
The reaction yields are an average of two replicates.
0.033 mL of iodobenzene (0.30 mmol, 1.0 equiv), 0.097 mL of tributylvinyltin
(0.33 mmol, 1.1 equiv), 5 mol % [Pd] catalyst, and 0.05 g of (0.03
mmol, 0.1 equiv) 1,3,5-trimethoxybenzene were dissolved in 1 mL dry,
degassed THF-d8. The reactions were carried
out in the dark and monitored every 2 h by 1H, 31P{1H}, and, when applicable, 19F NMR spectroscopy.
The reaction yields are an average of two replicates.
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