Quantitative Mass Spectrometry Proteomics
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Corresponding Organization : Harvard University
Protocol cited in 25 other protocols
Variable analysis
- None explicitly mentioned
- Protein level profiling
- Phosphorylation site localization
- Mass spectrometric data collected on an Orbitrap Fusion Lumos mass spectrometer
- Spectra converted to mzXML using a modified version of ReAdW.exe
- Database searching against the Saccharomyces Genome Database (SGD) concatenated with reversed protein sequences
- SEQUEST searches and linear discriminant analysis
- TMT tags on lysine residues and peptide N termini (+229.163 Da) and carbamidomethylation of cysteine residues (+57.021 Da) set as static modifications
- Oxidation of methionine residues (+15.995 Da) set as a variable modification
- For phosphorylation analysis, deamidation (+0.984) on asparagine and glutamine and phosphorylation (+79.966) on serine, threonine, and tyrosine set as variable modifications
- Peptide-spectrum matches (PSMs) adjusted to a 1% false discovery rate (FDR)
- PSM filtering performed using a linear discriminant analysis
- Phosphorylation site localization determined using the AScore algorithm with a threshold of 13 corresponding to 95% confidence
- Protein quantification by summing reporter ion counts across all matching PSMs, with reporter ion intensities adjusted to correct for isotopic impurities
- Signal-to-noise (S/N) measurements of peptides assigned to each protein summed and normalized to account for equal protein loading
- Each protein scaled such that the summed signal-to-noise for that protein across all channels was greater than 100, thereby generating a relative abundance (RA) measurement
- Positive control: Not specified
- Negative control: Not specified
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